Iron is one of the most abundant metals in Earth’s crust. It is found in natural fresh waters at levels ranging from 0.5 to 50 mg/l. Iron may also be present in drinking-water as a result of the use of iron coagulants or the corrosion of steel and cast iron pipes during water distribution.
Iron is an essential element in human nutrition, particularly in the iron(II) oxidation state. Estimates of the minimum daily requirement for iron depend on age, sex, physiological status and iron bioavailability and range from about 10 to 50 mg/ day.
As a precaution against storage in the body of excessive iron, in 1983, JECFA established a PMTDI of 0.8 mg/kg body weight, which applies to iron from all sources except for iron oxides used as coloring agents and iron supplements taken during pregnancy and lactation or for specific clinical requirements. An allocation of 10% of this PMTDI to drinking-water gives a value of about 2 mg/l, which does not present a hazard to health. The taste and appearance of drinking-water will usually be affected below this level.